The rare skincare question where the internet's scary answer is simply out of date.
Studies from the 1960s observed that niacinamide and ascorbic acid, mixed together and heated, could form a compound that made both less useful. The finding was real; the conditions were not realistic. At normal temperatures, with modern stabilized formulas, applied to skin rather than simmered in a beaker, the interaction is not a practical concern.
Thinnest first, as always. If both are serums, apply the more watery one first and wait a moment between layers. Order between these two matters far less than consistency: both reward daily use.
They approach tone from different directions. Vitamin C is an antioxidant that supports brightness and works well under morning sunscreen. Niacinamide supports the skin barrier and is one of the calmest, most forgiving actives in skincare. There are few skin types that cannot use it.
Very sensitive skin can find any stack of actives to be one active too many. If a routine with both leaves you flushed, the fix is fewer things at once, not abandoning either ingredient forever.
Color changes in vitamin C serums are usually oxidation from air and light over time, not a niacinamide reaction. A deeply orange or brown serum has aged out regardless of what you layer it with.
Niacinamide plus retinol is a classic gentle pairing. Adding vitamin C to that same routine is where sensitive skin may protest; morning vitamin C sidesteps it.
Not much. Thinner texture first is the only rule worth remembering.
A free iPhone app that knows the right order for your routine and warns you when ingredients clash. No account, no data collection, nothing to buy.